INTRODUCTION TO STARCH
1.1
MOLECULAR STRUCTURE
Chemical formula- (C6H10O5)n
Molecular weight - 162gm/mol
Starch contains both Amylose
Amylopectin
Amylose-
-is a linear polymer of
short 1,4 linked glucose chains.
-Typically the amylase fraction
is about 20-25% of starch molecules found in corn &
has a molecular weight of about 250,000. The percentage of amylase in the
starch is genetically determined. Genetic modification producing high amylose
(50-70%).
Amylopectin-
- is a branched polymer of
the basic repeating units of 1,4 linked glucose with branches of 1,6 linked glucose. The branching occurs approximately
one per twenty-five glucose units.
-comprises about 75-80% of
starch and has a molecular weight of about 50-550 million.
1.2
SOURCES OF STARCH
The main sources of starch are staple food as Maize (corn), wheat,
rice, potatoes, cassava,
Arrowroot and Sago, etc.
1.3 RAW
MATERIALS
-Dry maize -moisture 11-15% by weight
-Plant capacity 150 Ton per Day
-Process water- 6-8 m
-SO2 water – 160-180 grams sulfur per day
-prepared concentration nearly 3600 ppm
-Electricity – 2500 units per ton of grinding
1.4 SPECIAL STARCH PROPERTIES
COMPOSITION
Moisture – (11-15%)
Carbohydrates – (98-99%)
Protein- (0.5-0.7%)
Fiber- (0-0.5%)
Sulfated ash – (0-0.2%)
1.5 APPLICATIONS
Maize starch in its biological function, is used as an anti-agent
and a chemical catalyst. The world mohas been aware of the physical properties
of the maize starch for a while now, but researchersand scientists all over the
world are paying a great deal of the interest to biological aspects of
thecomplex carbohydrates, polymers.
Textile Industry
Maize starch has an extensive use in the Indian cotton textile
industry. Out of all starches maize starch has the quality to be removed in the
first wet process. It therefore can have an individual function at every stage
of textile manufacture.
a) It is used as an adhesive to strengthen the wrap yarn by
improving its resistance to abrasion while weaving.
b) Maize starch is immensely useful in printing to increase the
consistency of the printing paste.
c) It is used as finishing of the material, to change the
appearance after it has been dyed, bleached and printed.
d) Thread owes its glaze and bright shine to maize starch
e) Starch solution has very good penetration power and is used as
laundry stiffening agent.
Modified starch for the textile industry sizing
During weaving process, yarn is subjected to two kinds of
stresses. One is external frictional
stresses and shearing stresses and second is inner structural
stresses. An inadequately sized wrap can very often hinder the productivity of
even the most efficient automatic loom.
Among sized agent starch maintains its pre-eminence inspire of the
development of the synthetic products, starch keeps abreast of all new changes.
Application of sizing grade starch
All staple fibers, be they cotton polyesters mixtures, spun rayon
or wool, use sizing grade starches modified starches during the weaving process.
Food Industry
80% of the food diet is supplied by carbohydrates, and starch is
rich in it. Food starch manufacture is separation process to obtain powdered starch, which
is further used in sweeteners and modified starch products. Food starch therefore
plays:
a) They are nutritive stabilizers
b) They are the processing aids used in the manufacture of food
stuffs.
c) Modified starches provide uniformity in filling operations for
liquid and particulate formulations.
d) The use of pre-gelatinized starches controls the spread of cold
flow products in extrusions.
Examples- gravies,
sauces, puddings, chocolates, spreadable salad dressing, canning diary,confectionary baking, packaged mix,
frozen food.
Paper Industry
The very crispness of good quality paper depends on maize starch.
Besides accounting for a smooth surface texture, stiffness and rattle it increase the paper
strength so necessary for the printing.It is needed as ink penetration, sizing purposes, and as
a adhesive for coating of pigmented paper.
Adhesive Industry
High strength adhesives, paper glue, wood adhesives, label
adhesives, wall paper paste, etc all have a maize starch component. Gelletinized
starch is used as binder agent, while a number of adhesives such as dextrin’s
and modified starches are used in specific purposes.
Pharmaceutical Industry
Edible starch is being used as binding agent in tablets, etc.
besides this physical function it simultaneously acts as a dispersant agent. Starch granules are
very easily metabolized in the human body, so even a small amount of medicine absorbed by the
granules is quickly dispersed
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